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Exercise · Q21

Q.Explain the trend of the following in group 13 elements :
ionization enthalpy

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Step 1. State the general expectation. Ionization enthalpy usually falls down a group as atomic radius grows and the outer electron becomes easier to remove.

Step 2. Check the actual Table 9.2 values. First IE (kJ/mol): B 801, Al 577, Ga 579, In 558, Tl 589. From B to Al there is a large fall, as expected. But Ga (579) is very slightly higher than Al (577), and Tl (589) is higher again than In (558) — both irregular upward blips. …

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