Exercise · Q29
Q.What are silicones ? Where are they used ?
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Start your 14-day free trial to unlock the full solution →Step 1. Define silicones. Section 9.8.2: silicones are organosilicon polymers built from a repeating {R2SiO} unit (R = CH3 or C6H5), linked through Si-O-Si bonds; the name comes from this unit's empirical formula resembling a ketone, R2CO.
Step 2. Recall how they are made. Methyl- or aryl-substituted silicon chlorides (RnSiCl(4-n)) are hydrolysed to give silanols, which then undergo condensation polymerisation (losing water) into long -[SiR2-O]n- chains; adding (CH3)3SiCl caps the chain to control its length. …
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