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Exercise · Q25

Q.Draw the structure of the following
Orthophosphoric acid

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Step 1. Recall section 9.7.7. H3PO4's central phosphorus atom is described as tetrahedral, bonded to one oxygen by a P=O double bond and to three further oxygens, each carrying an ionizable acidic hydrogen (three P-OH groups).

Step 2. Write the structure in words (a drawing cannot be rendered here). Place phosphorus at the centre of a tetrahedron; one corner is a plain oxygen double-bonded to P (P=O); the other three corners are each an -OH group single-bonded to P (three P-OH bonds). All three OH hydrogens can ionize as H+, making the acid triprotic. …

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