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Question 45 of 66

Q.Which of the following is the first oxidation product of secondary alcohol?

(a) Alkene
(b) Aldehyde
(c) Ketone
(d) Carboxylic acid
Maharashtra MsbshseMaharashtra HSC (MSBSHSE) Board 2017MCQ· 1mImportance★★★★★
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A secondary alcohol's carbinol carbon has only one H, so oxidation removes it directly to give a ketone — no aldehyde stage is possible.

In a secondary alcohol, R2CH−OHR_2CH-OH, the carbon bearing the −OH-OH group has only one hydrogen attached. On oxidation (e.g. with acidified K2Cr2O7K_2Cr_2O_7 or KMnO4KMnO_4), that single C–H bond and the O–H bond are both removed to directly form a carbonyl (C=O) group, giving a ketone, R2C=OR_2C=O. (This differs from a primary alcohol, which is first oxidised to an aldehyd …

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