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Question 59 of 66

Q.Convert the following:

(i) Ethyl alcohol into ethyl acetate
(ii) Phenol into benzene
(iii) Diethyl ether into ethyl chloride
Maharashtra MsbshseMaharashtra HSC (MSBSHSE) Board 2023Subjective· 3mImportance★★★★★
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Fischer esterification, zinc-dust reduction, and acidic ether cleavage carry out the three requested conversions.

  1. Ethyl alcohol into ethyl acetate: Fischer esterification with acetic acid, acid-catalysed: C2H5OH+CH3COOH⇌ΔH2SO4CH3COOC2H5+H2OC_2H_5OH + CH_3COOH \underset{H_2SO_4}{\overset{\Delta}{\rightleftharpoons}} CH_3COOC_2H_5 + H_2O
  2. Phenol into benzene: distillation of phenol with zinc dust reduces/deoxygenates it to benzene: C6H5OH+Zn→ΔC6H6+ZnOC_6H_5OH + Zn \xrightarrow{\Delta} C_6H_6 + ZnO …

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