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Question 63 of 66

Q.Write the structural formula and IUPAC name of the alcohol having molecular formula C4_4H10_{10}O which does not undergo oxidation under normal condition.

Maharashtra MsbshseMaharashtra HSC (MSBSHSE) Board 2025Subjective· 2mImportance★★★★★
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The tertiary alcohol among C4H10OC_4H_{10}O isomers, (CH3)3COH(CH_3)_3COH (2-methylpropan-2-ol), has no carbinol H, so it resists normal oxidation.

Alcohols are oxidised by mild oxidising agents (acidified K2Cr2O7K_2Cr_2O_7/KMnO4KMnO_4) via loss of a hydrogen from the carbinol (−CH−OH-CH-OH) carbon: primary alcohols oxidise to aldehydes/acids, secondary alcohols to ketones. Tertiary alcohols, however, have NO hydrogen on the carbinol carbon (it is attached to three carbon groups), so they cannot undergo this oxidation under normal conditions.

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