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Question 109 of 119

Q.Explain the trends in the following atomic properties of group 16 elements:

(i) Atomic radii
(ii) Ionisation enthalpy
(iii) Electronegativity
(iv) Electron gain enthalpy
Maharashtra MsbshseMaharashtra HSC (MSBSHSE) Board 2022Subjective· 2mImportance★★★★★
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Standard periodic trends apply down group 16, with oxygen's electron gain enthalpy as the usual exception.

  1. Atomic radii: Increase down the group (O → S → Se → Te → Po) as successive shells are added, outweighing the increase in nuclear charge.
  2. Ionisation enthalpy: Decreases down the group, since atomic size increases and the outer electrons are progressively farther from and better shielded from the nucleus, making them easier to remove.
  3. Electronegativity: Decreases down the group, as increasing atomic size reduces the nucleus's pull on a shared electron pair/an incoming electron. …

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