Question 116 of 119
Q.Write anomalous behaviour of oxygen with respect to:
(i) Atomicity
(ii) Oxidation state
(iii) Magnetic property
(iv) Nature of hydrides.
Maharashtra MsbshseMaharashtra HSC (MSBSHSE) Board 2025Subjective· 2mImportance★★★★★
97% · 116/119 Questions
You're viewing a preview — the full solution, concept, methods & PYQ mapping are locked.
Start your 14-day free trial to unlock the full solution →O is diatomic (vs polyatomic S/Se/Te), shows only up to +2 (vs +6), O is paramagnetic, and HO is a liquid (H-bonded) unlike gaseous HS/HSe/HTe.
- Atomicity: oxygen exists as a diatomic molecule, , while the heavier group-16 members (S, Se, Te) exist as larger polyatomic molecules, e.g. (puckered ring), owing to oxygen's strong tendency to form – multiple bonds instead of long catenated chains.
- Oxidation state: oxygen (being the second most electronegative element) shows a very restricted range of oxidation states, mainly , with in peroxides and rarely (with F, as in ); it never shows the higher positive states (, ) that S, Se, Te readily show (e.g. ), because oxygen lacks accessible d orbitals.
- Magnetic property: is paramagnetic due to two unpaired electrons in its antibonding molecular orbitals (as explained by MO theory), while the corresponding compounds/allotropes of S, Se, Te are diamagnetic. …
Unlock everything free for 14 days
- Full step-by-step solutions
- Concept-first explanations
- Methods, shortcuts & mistakes
- PYQ mapping + timed mock tests
Full access for 14 days. No credit card required.