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Chemistry · Ch 1 — Solid State

Types of unit cell

1.4.3

Types of unit cell

There are four types of unit cell, distinguished by where the constituent particles are located within the cell.

i. Primitive or simple unit cell : Constituent particles are present at the eight corners of the unit cell only.

ii. Body-centred unit cell : In addition to the particles at the eight corners, one particle is present at the centre of the body of the unit cell.

iii. Face-centred unit cell : In addition to the particles at the eight corners, one particle is present at the centre of each of the six faces of the unit cell.

iv. Base-centred unit cell : In addition to the particles at the eight corners, one particle is present at the centre of each of any two opposite faces of the unit cell. …