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Chemistry · Ch 2 — Solutions

Boiling Point Elevation and Concentration of Solute

2.8.2

Boiling Point Elevation and Concentration of Solute

The boiling point elevation is directly proportional to the molality of the solution. Thus,

ΔTb∝morΔTb=Kb m...(2.13)\Delta T_b \propto m \quad \text{or} \quad \Delta T_b = K_b\,m \qquad \text{...(2.13)}

where mm is the molality of the solution. The proportionality constant KbK_b is called the boiling point elevation constant or molal elevation constant or ebullioscopic constant.

If m=1m = 1, then ΔTb=Kb\Delta T_b = K_b. Thus, the ebullioscopic constant is the boiling point elevation produced by a 1 molal solution.

Units of KbK_b : Kb=ΔTbm=Kmol kg−1=K kg mol−1K_b = \dfrac{\Delta T_b}{m} = \dfrac{\mathrm{K}}{\mathrm{mol\,kg^{-1}}} = \mathrm{K\,kg\,mol^{-1}}

Remember

Remember...

KbK_b and ΔTb\Delta T_b are the differences between two temperatures. Hence, their values will be the same in K or in 0^0C. …