Skip to content

Chemistry · Ch 2 — Solutions

Molar Mass of Solute from Boiling Point Elevation

2.8.3

Molar Mass of Solute from Boiling Point Elevation

The Eq. (2.13) is ΔTb=Kbm\Delta T_b = K_b m.

Suppose we prepare a solution by dissolving W2\mathrm{W_2} g of solute in W1\mathrm{W_1} g of solvent. The moles of solute in W1\mathrm{W_1} g of solvent are W2M2\dfrac{W_2}{M_2}, where M2M_2 is the molar mass of the solute. The mass of the solvent, converted from grams to kilograms, is W11000\dfrac{W_1}{1000} kg.

Recall the expression for molality, mm:

m=moles of solutemass of solvent in kg=W2/M2 molW1/1000 kg=1000 W2M2W1 mol kg−1...(2.14)m = \frac{\text{moles of solute}}{\text{mass of solvent in kg}} = \frac{W_2/M_2\ \mathrm{mol}}{W_1/1000\ \mathrm{kg}} = \frac{1000\,W_2}{M_2 W_1}\ \mathrm{mol\,kg^{-1}} \qquad \text{...(2.14)}

Substitution of this value of mm in Eq. (2.13) gives

ΔTb=Kb 1000 W2M2W1\Delta T_b = K_b\,\frac{1000\,W_2}{M_2 W_1}

Hence,

M2=1000 KbW2ΔTbW1...(2.15)M_2 = \frac{1000\,K_b W_2}{\Delta T_b W_1} \qquad \text{...(2.15)} …