The Eq. (2.13) is ΔTb=Kbm.
Suppose we prepare a solution by dissolving W2 g of solute in W1 g of solvent. The moles of solute in W1 g of solvent are M2W2, where M2 is the molar mass of the solute. The mass of the solvent, converted from grams to kilograms, is 1000W1 kg.
Recall the expression for molality, m:
m=mass of solvent in kgmoles of solute=W1/1000 kgW2/M2 mol=M2W11000W2 molkg−1...(2.14)
Substitution of this value of m in Eq. (2.13) gives
ΔTb=KbM2W11000W2
Hence,
M2=ΔTbW11000KbW2...(2.15) …