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Long Answer Questions · Q11

Q.Explain the inverse linear dependence of stopping potential on the incident wavelength in a photoelectric effect experiment.

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Einstein's photoelectric equation, in terms of stopping potential, is eV0=KEmax=hν−ϕ0eV_0=KE_{max}=h\nu-\phi_0. Since frequency and wavelength are related by ν=c/λ\nu=c/\lambda, substituting gives\n\neV0=hcλ−ϕ0⟹V0=hceλ−ϕ0eeV_0 = \frac{hc}{\lambda} - \phi_0 \qquad\Longrightarrow\qquad V_0 = \frac{hc}{e\lambda} - \frac{\phi_0}{e}\n\nThis shows that V0V_0 is NOT linear in λ\lambda itself, but is linear in 1/λ\boldsymbol{1/\lambda}: plotting V0V_0 against 1/λ1/\lambda gives a straight line of slope hc/ehc/e (a universal constant, same for every metal) and intercept −ϕ0/e-\phi_0/e (which depends on the emitter material). As the wavelength λ\lambda INCREASES, 1/λ1/\lambda decreases, and since V0V_0 is directly proportional to 1/λ1/\lambda (apart from the constant offset −ϕ0/e-\phi_0/e), V0V_0 correspondingly DECREASES -- an inverse relationship between V0V_0 and λ\lambda, even though the underlying mathematical dependence is a straight line when plotted against 1/λ1/\lambda rather than against λ\lambda directly.\n\nPhysically, this makes sense: a longer wavelength means lower frequency, hence a lower-energy photon hν=hc/λh\nu=hc/\lambda; since KEmax=hν−ϕ0KE_{max}=h\nu-\phi_0, a lower photon energy directly means a lower maximum kinetic energy for the photoelectrons, and hence a lower stopping potential is needed to turn them back. As λ\lambda keeps increasing, V0V_0 keeps falling until it reaches exactly zero at the THRESHOLD WAVELENGTH λ0=hc/ϕ0\lambda_0=hc/\phi_0 (equivalently, the threshold frequency ν0=ϕ0/h\nu_0=\phi_0/h) -- beyond which no photoelectrons are emitted at all, however long the wavelength is stretched. [!ANSWER] V0=hceλ−ϕ0eV_0=\frac{hc}{e\lambda}-\frac{\phi_0}{e}: a straight line in V0V_0 vs 1/λ1/\lambda, so V0V_0 falls off inversely as λ\lambda grows.

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