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Long Answer Questions · Q13

Q.Explain what do you understand by the de Broglie wavelength of an electron. Will an electron at rest have an associated de Broglie wavelength? Justify your answer.

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The de Broglie wavelength of an electron (or any material particle) of mass m moving with speed v is given by de Broglie's relation, λ=hp=hmv\lambda=\dfrac{h}{p}=\dfrac{h}{mv}, where p=mvp=mv is the electron's momentum. This is the wavelength of the 'matter wave' de Broglie proposed is associated with every moving particle, arrived at by extending the photon relation p=h/λp=h/\lambda (originally derived for light) to material particles as well, on the basis of nature's symmetry between wave and particle descriptions.\n\nFor an electron at REST, its velocity v=0v=0, so its momentum p=mv=0p=mv=0 as well. Substituting into λ=h/p\lambda=h/p gives λ=h/0\lambda=h/0, which is mathematically UNDEFINED (or, taking the limit as v→0+v\to0^+, λ→∞\lambda\to\infty). An infinite wavelength has no physical meaning as a genuine, observable 'matter wave' -- a wave needs a finite momentum to have a finite, measurable wavelength.\n\nSo the honest answer is: NO, an electron truly at rest does not have a meaningful (finite) de Broglie wavelength. The de Broglie wave picture is inherently tied to the particle's MOTION -- specifically its momentum -- and only becomes physica …

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