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Exercises · 2.40

Q.In Rutherford's experiment, generally the thin foil of heavy atoms, like gold, platinum etc. have been used to be bombarded by the α-particles. If the thin foil of light atoms like aluminium etc. is used, what difference would be observed from the above results?

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Using a light-atom foil (e.g., aluminium) instead of a heavy one (e.g., gold) in Rutherford’s experiment reduces the number of large-angle scatterings and the fraction of α-particles that bounce back, because the lighter nucleus imparts less Coulomb repulsion and is itself pushed back more — the scattering pattern shifts toward smaller angles.

Rutherford’s gold-foil experiment revealed that atoms have a tiny, dense, positively charged nucleus. The key observation was that a small fraction of α-particles (about 1 in 8000 for gold) were scattered through angles greater than 90°, and some even bounced back. This happens because the α-particle and the gold nucleus repel each other strongly due to their positive charges. The closer the α-particle gets to the nucleus, the larger the scattering angle.

Now, if you replace the gold foil with a foil made of a light element like aluminium, the physics changes in a fundamental way. The crucial difference is the mass of the nucleus. Gold has a mass number of about 197, while aluminium is about 27. An α-particle has a mass number of 4. So the α-particle is much lighter than a gold nucleus, but it is comparable in mass to an aluminium nucleus.

Here’s why that matters, step by step.

  1. The centre-of-mass effect. In Rutherford’s original derivation, he assumed the target nucleus is infinitely heavy — it stays fixed. That’s an excellent approximation for gold: the α-particle (mass 4) hits a nucleus of mass 197, so the nucleus barely recoils. But for aluminium (mass 27), the nucleus is only about 7 times heavier than the α-particle. The nucleus will recoil significantly, carrying away some of the incident kinetic energy. This reduces the energy available for the α-particle to overcome the Coulomb barrier and get close to the nucleus.

  2. The distance of closest approach. For a head-on collision, the distance of closest approach r0r_0 is given by equating the initial kinetic energy KK to the electrostatic potential energy at the turning point:

K=14πϵ0(2e)(Ze)r0K = \frac{1}{4\pi\epsilon_0} \frac{(2e)(Ze)}{r_0}

where ZZ is the atomic number (79 for gold, 13 for aluminium). So r0∝Z/Kr_0 \propto Z/K. But here’s the catch: in a collision with a light nucleus, the kinetic energy in the centre-of-mass frame is less than the lab-frame kinetic energy because the nucleus recoils. The effective kinetic energy available for the Coulomb repulsion is

Kcm=mAlmAl+mαKlabK_{\text{cm}} = \frac{m_{\text{Al}}}{m_{\text{Al}} + m_\alpha} K_{\text{lab}}

For gold, this factor is nearly 1; for aluminium, it’s about 27/(27+4)≈0.8727/(27+4) \approx 0.87. So the α-particle cannot get as close to an aluminium nucleus as it can to a gold nucleus for the same incident energy.

  1. Scattering probability and angle. The famous Rutherford scattering formula gives the number of particles scattered into a given solid angle:

dNdΩ=(Ze216πϵ0K)2Ntsin⁡4(θ/2)\frac{dN}{d\Omega} = \left( \frac{Ze^2}{16\pi\epsilon_0 K} \right)^2 \frac{N_t}{\sin^4(\theta/2)}

Here NtN_t is the number of target nuclei per unit area. Notice the Z2Z^2 dependence. For gold (Z=79Z=79) versus aluminium (Z=13Z=13), the ratio is (79/13)2≈37(79/13)^2 \approx 37. That means, for the same foil thickness and incident energy, gold scatters about 37 times more α-particles into a given angle than aluminium does. But this formula assumes a fixed nucleus. For a light nucleus, the formula must be modified by replacing KK with KcmK_{\text{cm}} and the scattering angle θ\theta in the lab frame is different from the centre-of-mass angle. The net effect is that large-angle scattering becomes much rarer.

  1. The fraction of backscattered particles. The fraction of α-particles scattered through angles greater than 90° is roughly proportional to Z2/K2Z^2 / K^2. For gold, this fraction is about 1.3×10−41.3 \times 10^{-4} (1 in 8000). For aluminium, using the same incident energy, the fraction drops by a factor of about (79/13)2≈37(79/13)^2 \approx 37, so it becomes roughly 3.5×10−63.5 \times 10^{-6} — that’s about 1 in 300,000. In practice, you would observe almost no α-particles bouncing back from an aluminium foil. …

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