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Question 64 of 71

Q.The IUPAC name of the compound CH3-CH(OH)-CH2-CH=CH-CH3 :

(a) hex-2-en-4-ol
(b) hex-4-en-2-ol
(c) hex-2-en-4-al
(d) hex-4-en-2-al
Puducherry TnboardTamil Nadu HSC First Year (DGE) Board 2023MCQ· 1mImportance★★★★★
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The compound is a hexene bearing an -OH group; numbering the chain from the end closest to the -OH group (the senior/principal characteristic group) gives hex-4-en-2-ol.

The given structure is CH3-CH(OH)-CH2-CH=CH-CH3, a straight chain of six carbons containing one C=C double bond and one -OH group. For IUPAC naming of an alcohol, the principal characteristic group (here -OH, named with the suffix -ol) must get the lowest possible locant when there is a choice, ahead of the locant for the double bond.

Numbering from the left end (the end nearer -OH):

C1(CH3) - C2(CH-OH) - C3(CH2) - C4(CH=) - C5(=CH) - C6(CH3)

-OH is on C2, the double bond is between C4 and C5.

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