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Question 81 of 83

Q.In an Organic compound, Phosphorus is estimated as :

(a) Mg2P2O7
(b) Mg3(PO4)2
(c) H3PO4
(d) P2O5
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The question asks the form in which phosphorus is estimated during the quantitative analysis of an organic compound.

Phosphorus is estimated as magnesium pyrophosphate, Mg2P2O7.

In the estimation of phosphorus, a known mass of the organic compound is heated with an oxidising agent (such as fuming nitric acid) so that the phosphorus is converted to phosphoric acid (H3PO4). This is then precipitated as magnesium ammonium phosphate (MgNH4PO4) by adding magnesia mixture. On strong ignition, the magnesium ammonium phosphate is converted to magnesium pyrophosphate, Mg2P2O7, which is weighed. …

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