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Question 54 of 71

Q.The ratio gamma = Cp/Cv for a gas mixture consisting of 8 g of helium and 16 g of oxygen is :

(a) 27/17
(b) 23/15
(c) 17/27
(d) 15/23
Puducherry TnboardTamil Nadu HSC First Year (DGE) Board 2022MCQ· 1mImportance★★★★★
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Find the number of moles of each gas, use the correct degrees of freedom for each (monatomic He: f=3; diatomic O2: f=5) to get each gas's Cv and Cp, mole-average these for the mixture, and take the ratio.

Step 1 — moles of each gas:

Helium: mass = 8 g, molar mass M(He) = 4 g/mol ⇒ n(He) = 8/4 = 2 mol.

Oxygen: mass = 16 g, molar mass M(O2) = 32 g/mol ⇒ n(O2) = 16/32 = 0.5 mol.

Step 2 — molar specific heats of each gas:

Helium is monatomic (f = 3): Cv(He) = (3/2)R, Cp(He) = (5/2)R.

Oxygen is diatomic (f = 5, rigid, room temperature): Cv(O2) = (5/2)R, Cp(O2) = (7/2)R.

Step 3 — mixture's Cv and Cp (mole-weighted average):

Cv(mix) = [n(He)·Cv(He) + n(O2)·Cv(O2)] / [n(He)+n(O2)] …

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