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Question 52 of 71

Q.List the factors affecting the mean free path.

Puducherry TnboardTamil Nadu HSC First Year (DGE) Board 2020Subjective· 2mImportance★★★★★
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Mean free path λ ∝ 1/(n d^2), so it is governed by the number density of molecules, their diameter, and — through these — the temperature and pressure of the gas.

The mean free path is the average distance a gas molecule travels between successive collisions with other molecules. It is given approximately by:

λ = 1 / (√2 π d^2 n)

where d is the diameter of a molecule and n is the number density of molecules (number of molecules per unit volume).

From this expression, the factors affecting the mean free path are:

  1. Number density of molecules (n): A larger number density means molecules are packed closer together, so collisions happen more often and the mean free path is shorter (λ ∝ 1/n).

  2. Diameter of the molecule (d): A larger molecular diameter increases the effective collision cross-section, making collisions more likely, so the mean free path is shorter (λ ∝ 1/d^2).

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