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Choose the Best Answer · Q11

Q.What is the activation energy for a reaction if its rate doubles when the temperature is raised from 200 K to 400 K? (R=8.314 JK−1mol−1R=8.314\ \text{JK}^{-1}\text{mol}^{-1})

(a) 234.65 kJ mol−1234.65\ \text{kJ mol}^{-1}
(b) 434.65 kJ mol−1434.65\ \text{kJ mol}^{-1}
(c) 2.305 kJ mol−12.305\ \text{kJ mol}^{-1}
(d) 334.65 J mol−1334.65\ \text{J mol}^{-1}
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Step 1. Use the two-temperature Arrhenius form: ln⁡k2k1=EaR(1T1−1T2)\ln\dfrac{k_2}{k_1}=\dfrac{E_a}{R}\left(\dfrac{1}{T_1}-\dfrac{1}{T_2}\right), with k2/k1=2k_2/k_1=2 (rate doubles), T1=200T_1=200 K, T2=400T_2=400 K.

Step 2. 1T1−1T2=1200−1400=2−1400=1400 K−1\dfrac{1}{T_1}-\dfrac{1}{T_2}=\dfrac{1}{200}-\dfrac{1}{400}=\dfrac{2-1}{400}=\dfrac{1}{400}\ \text{K}^{-1}. …

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