Choose the Best Answer · Q9
Q.Consider the following statements:
(i) increase in concentration of the reactant increases the rate of a zero order reaction.
(ii) rate constant k is equal to collision frequency A if
(iii) rate constant k is equal to collision frequency A if
(iv) a plot of vs T is a straight line.
(v) a plot of vs is a straight line with a positive slope. Correct statements are
(a)
(ii) only
(b)
(ii) and
(iv)
(c)
(ii) and
(v)
(d) (i),
(ii) and (v)
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Start your 14-day free trial to unlock the full solution →Step 1. Statement (i) is FALSE: a zero order reaction's rate is, by definition, INDEPENDENT of reactant concentration -- increasing concentration does not increase its rate.
Step 2. Statement (ii) is TRUE: from , setting gives , so .
Step 3. Statement (iii) is FALSE: setting gives , so , not . …
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