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Write Brief Answer · Q10

Q.Arrange the following solutions in decreasing order of specific conductance.

i) 0.01M KCl
ii) 0.005M KCl
iii) 0.1M KCl
iv) 0.25M KCl
v) 0.5M KCl
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Step 1. Specific conductance κ measures the conductance of a fixed unit volume of solution, so it directly reflects how many ions are packed into that volume.

Step 2. For a strong electrolyte such as KCl, higher concentration means more ions per unit volume, and hence generally HIGHER specific conductance — this is the opposite trend to molar conductance, which is normalised per mole and so falls with rising concentration. …

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