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Choose the Best Answer · Q16

Q.In the H2-O2\text{H}_2\text{-O}_2 fuel cell, the reaction that occurs at the cathode is

(a) O2(g)+2H2O(l)+4e−→4OH−(aq)\text{O}_2\text{(g)} + 2\text{H}_2\text{O(l)} + 4e^{-} \rightarrow 4\text{OH}^{-}\text{(aq)}
(b) H+(aq)+OH−(aq)→H2O(l)\text{H}^{+}\text{(aq)} + \text{OH}^{-}\text{(aq)} \rightarrow \text{H}_2\text{O(l)}
(c) 2H2(g)+O2(g)→2H2O(g)2\text{H}_2\text{(g)} + \text{O}_2\text{(g)} \rightarrow 2\text{H}_2\text{O(g)}
(d) H++e−→12H2\text{H}^{+} + e^{-} \rightarrow \dfrac{1}{2}\text{H}_2
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Step 1. In the hydrogen-oxygen fuel cell, oxidation of H₂ occurs at the anode and reduction of O₂ occurs at the cathode — recall the two half-reactions exactly as stated in the fuel cells section.

Step 2. The cathode (reduction) half-reaction is O2(g)+2H2O(l)+4e−→4OH−(aq)\text{O}_2\text{(g)} + 2\text{H}_2\text{O(l)} + 4e^{-} \rightarrow 4\text{OH}^{-}\text{(aq)} — oxygen gains 4 electrons per molecule and combines with water to regenerate hydroxide ions in the alkaline KOH electrolyte. …

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