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Question 49 of 62

Q.Arrange the order of increasing atomic volumes in:

(a) Li, Na and K
(b) C, N and O
(c) Ca, Sr and Ba
Tamil Nadu DgeTamil Nadu HSC First Year (DGE) Board 2018Subjective· 3mImportance★★★★★
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Atomic volume increases going down a group (more shells added) and increases going right-to-left across a period - i.e., decreases left to right across a period.

(a) Li, Na and K are all in Group 1 (alkali metals), one below the other. Going down a group, a new principal energy shell is added and the effective nuclear charge experienced by the outermost electron doesn't increase proportionally, so atomic size (and atomic volume) increases down the group:

Li < Na < K

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