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Choose the Best Answer · Q18

Q.The stability of +1 oxidation state increases in the sequence

a) Al < Ga < In < Tl
b) Tl < In < Ga < Al
c) In < Tl < Ga < Al
d) Ga< In < Al < Tl
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Step 1. The inert pair effect (Section 2.1.6) makes the ns² electron pair increasingly reluctant to take part in bonding as group 13 is descended, favouring the +1 state (two less than the +3 group state) more and more strongly for the heavier elements.

Step 2. At the top of the group, Al³⁺ is more stable than Al⁺ — i.e. +1 is the LEAST favoured state for aluminium among the five elements.

Step 3. At the bottom of the group, the chapter states explicitly that Tl⁺ is MORE stable than Tl³⁺ — i.e. +1 is the MOST favoured, most stable state for thallium of the five. …

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