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Choose the Best Answer · Q9

Q.The basic structural unit of silicates is (NEET)

a) (SiO₃)²⁻
b) (SiO₄)²⁻
c) (SiO)⁻
d) (SiO₄)⁴⁻
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Step 1. The chapter defines a silicate as any mineral built from [SiO₄]⁴⁻ tetrahedra linked together in different patterns (Section 2.3.9).

Step 2. This unit — one silicon at the centre, four oxygens at the corners of a tetrahedron — is the single common structural building block of every silicate class described (ortho, pyro, cyclic, chain, sheet and 3-D silicates); larger silicate ions are always built by linking multiple [SiO₄]⁴⁻ tetrahedra and sharing some of their corner oxygens.

Step 3. The charge is 4- because silicon is +4 and each of the four oxygens contributes -2, giving a net of +4 + 4(-2) = -4 for the unshared, discrete ion. …

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