Q.A molecule of a substance has a permanent electric dipole moment of magnitude 10−29 C m. A mole of this substance is polarised (at low temperature) by applying a strong electrostatic field of magnitude 106 V m−1. The direction of the field is suddenly changed by an angle of 60∘. Estimate the heat released by the substance in aligning its dipoles along the new direction of the field. For simplicity, assume 100% polarisation of the sample.
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🔒 Start your 14-day free trial to unlock the full solution →Concept understanding — Dipole Alignment Energy
Dipole Alignment Energy — From Intuition to Formula
Imagine you have a tiny bar magnet — a compass needle. You know it always turns to point north. But what if you try to hold it pointing east? You feel a torque, a twisting force that wants to rotate it back. If you let go, it snaps to align with the field.
That "snap" releases energy. The energy that was stored in the misaligned configuration is called dipole alignment energy (or potential energy of a dipole in an external field).
The Core Intuition
A dipole (like a compass needle or a polar molecule) has two opposite "poles" — a north and a south, or a positive and a negative charge. When placed in an external field:
- Aligned (parallel to the field): the dipole is in its lowest energy state — like a ball at the bottom of a valley.
- Anti-aligned (opposite to the field): the dipole is in its highest energy state — like a ball balanced at the top of a hill.
- Perpendicular: the energy is somewhere in between.
The energy depends on how much the dipole is twisted away from the field direction. The more you force it to point against the field, the more energy you store — like winding a spring.
The Precise Statement
For an electric dipole with dipole moment p placed in a uniform external electric field E, the potential energy of alignment is:
U=−p⋅E=−pEcosθ
where θ is the angle between p and E.
For a magnetic dipole (like a current loop or a compass needle) with magnetic moment μ in a magnetic field B:
U=−μ⋅B=−μBcosθ
Why the Negative Sign?
This is the part that confuses most students. Let's break it down.
When θ=0∘ (aligned), cosθ=1, so U=−pE. This is the minimum energy — the most stable configuration.
When θ=180∘ (anti-aligned), cosθ=−1, so U=+pE. This is the maximum energy — the least stable.
The negative sign is a convention that makes the aligned state the lowest energy. Think of it this way: the field does positive work to rotate the dipole from anti-aligned to aligned, so the dipole loses potential energy. The formula captures that loss as a negative value relative to the zero-energy reference (which is usually taken at θ=90∘, where U=0).
A common mistake: thinking U=p⋅E (without the minus sign). That would make the aligned state highest energy — physically wrong. The dipole wants to align, so aligned must be lowest energy.
What It Physically Means
The alignment energy tells you:
- How much work an external agent must do to rotate the dipole from aligned to some angle θ.
- How stable the dipole is in a given orientation — the deeper the energy well (larger p or E), the harder to knock it out of alignment.
- The torque on the dipole: τ=−dθdU=−pEsinθ, which matches the familiar τ=p×E.
A Quick Example
A water molecule has a permanent electric dipole moment p=6.2×10−30 C⋅m. In an electric field of 106 N/C (a strong laboratory field): …
Concept: Dipole Alignment Energy, U=−pEcosθ. The dipoles start aligned with the old field, i.e. at 60∘ to the new field, then relax to 0∘; the released energy appears as heat.
- Heat per dipole =U60∘−U0∘=(−pEcos60∘)−(−pEcos0∘)=pE(1−21)=21pE.
- For one mole (NA=6.022×1023): Q=21NApE. …
The dipoles begin aligned with the old field (so 60∘ from the new one) and relax to alignment; the released energy is Q=21NApE=21×6.022×1023×10−29×106≈3.0J.
The physics
A permanent dipole in a field has potential energy U=−p⋅E=−pEcosθ, minimum (−pE) when aligned. When the field direction is suddenly turned by 60∘, the dipoles — still pointing the old way — are now at 60∘ to the new field. As they swing round to align with it, their potential energy drops, and that energy is dissipated as heat.
The dipoles do not start aligned with the new field; they start 60∘ from it (their old alignment direction).
Step 1 — Heat released by one dipole
Ui=−pEcos60∘=−21pE,Uf=−pEcos0∘=−pE.
q=Ui−Uf=−21pE−(−pE)=21pE.
Step 2 — Scale to one mole (100% polarised) …
Method: Heat Released When a Field Reorients a Population of Dipoles
This method applies whenever a strong external field suddenly changes direction and a collection of permanent dipoles — already aligned with the old field direction — relaxes to align with the new one, releasing energy as heat.
Steps
Step 1: Identify the dipole's initial and final angle relative to the new field direction
The dipole is not initially aligned with the new field — it is still pointing along the old field direction, which now makes some angle θ with the new direction (equal to the angle through which the field was rotated). The final angle, once the dipole has settled, is 0∘ (fully aligned).
Step 2: Write the potential energy at each angle using U=−pEcosθ
Ui=−pEcosθ,Uf=−pEcos0∘=−pE
Step 3: The heat released per dipole is the drop in potential energy
qper dipole=Ui−Uf …
Showing the 12 most recent of 34 on this concept.
- TG EAPCET 2026Set eng-2026-05-09-FN1 markMCQQ.An iron rod of mass 2 kg and length 1.5 m is supplied 18.4 kJ of heat. If the specific heat capacity of iron is 460Jkg−1K−1 and its coefficient of linear expansion is 1.2×10−5∘C−1, then the increase in the length of the rod is (A) 0.24 mm (B) 0.36 mm (C) 0.12 mm (D) 0.18 mm
›Reveal solutionSolution
The rod’s temperature rise is found from the heat supplied, mass, and specific heat capacity; then the linear expansion formula gives the increase in length. The final increase is 0.36 mm, so option (B) is correct.
Concept & Intuition
When heat is added to a solid, its temperature rises according to Q=mcΔT. Once we know the temperature change, the rod expands linearly: ΔL=αL0ΔT. The key is to connect the thermal energy input to the dimensional change via the temperature rise — a two‑step process that is straightforward if we keep units consistent.
- Find the temperature rise from the heat supplied The heat added is Q=18.4 kJ=18.4×103 J. Mass m=2 kg, specific heat c=460 J kg−1K−1. Using Q=mcΔT:
ΔT=mcQ=2×46018.4×103=92018400=20 ∘C (or K).
So the rod’s temperature increases by 20 ∘C.
- Apply the linear expansion formula Original length L0=1.5 m, coefficient α=1.2×10−5 ∘C−1. The increase in length is:
ΔL=αL0ΔT=(1.2×10−5)×1.5×20.
Compute step by step:
1.2×10−5×1.5=1.8×10−5,
then
1.8×10−5×20=3.6×10−4 m.… - TG EAPCET 2026Set eng-2026-05-09-FN1 markMCQQ.The rms value of electric field at a distance of 6 m from a 100 W bulb of efficiency 1.2% is (A) 4Vm−1 (B) 1Vm−1 (C) 2Vm−1 (D) 3Vm−1
›Reveal solutionSolution
The rms electric field is found by converting the bulb’s electrical power into radiated intensity, then using the relation between intensity and rms electric field. The result is 1 Vm−1, so the correct option is (B).
Concept & Intuition
A light bulb radiates electromagnetic waves. Only a fraction of its electrical power (the efficiency) becomes light. At a distance r, that power spreads uniformly over a sphere of area 4πr2, giving the intensity I (power per unit area). For an electromagnetic wave in vacuum, the intensity is related to the rms electric field Erms by I=ε0cErms2. So we can work backwards: from the bulb’s radiated power, find I, then solve for Erms.
Step-by-step solution
- Find the actual radiated power The bulb draws 100 W, but only 1.2% is converted to light.
Prad=100×1001.2=1.2 W
- Compute the intensity at 6 m The radiated power spreads uniformly over a sphere of radius r=6 m.
I=4πr2Prad=4π×361.2=144π1.2=120π1 W/m2
- Relate intensity to rms electric field For a plane electromagnetic wave in vacuum, the time‑averaged intensity is
I=ε0cErms2
where ε0=8.85×10−12 F/m and c=3×108 m/s.
- Solve for Erms
Erms=ε0cI=(8.85×10−12)(3×108)1/(120π)
First compute the denominator:
ε0c=(8.85×10−12)(3×108)=2.655×10−3… - TG EAPCET 2026Set eng-2026-05-10-AN1 markMCQQ.At a distance of 20 cm from the centre of a charged conducting sphere of radius 10 cm, the electric field due to the sphere is 9000NC−1. If an electric charge of 3μC is placed at a distance of 30 cm from the centre of the sphere, then the electrostatic force acting on the charge is (A) 9 mN (B) 12 mN (C) 18 mN (D) 24 mN
›Reveal solutionSolution
Outside a charged sphere the field is E=kQ/r2; use the given field to find kQ, then the field (and force) at 30 cm. Force =12 mN (B).
Step 1 — Find kQ from the given data.
Outside the sphere it behaves like a point charge at the centre:
E=r2kQ⇒kQ=Er2=9000×(0.20)2=360 N m2C−1
Step 2 — Field at 30 cm from the centre. …
- TG EAPCET 2026Set eng-2026-05-10-AN1 markMCQQ.The amplitude of the magnetic field of a plane electromagnetic wave travelling along positive x-axis in vacuum is 6 mT. A particle of charge 5 μC is travelling with a velocity of 6×105 ms−1 along the positive y-axis. If the magnetic field is oriented along positive z-axis, then the maximum force exerted on the particle due to electric field of the wave is (A) 15 N (B) 18 N (C) 9 N (D) 12 N
›Reveal solutionSolution
The maximum electric force on the particle is found by first relating the electric and magnetic field amplitudes in an EM wave via E0=cB0, then using F=qE0. The result is 9 N, so the correct option is (C).
Concept & Intuition
In a plane electromagnetic wave in vacuum, the electric and magnetic fields are perpendicular to each other and to the direction of propagation. Their amplitudes are related by E0=cB0, where c is the speed of light. The force from the magnetic field depends on velocity, but the question asks specifically for the maximum force due to the electric field — that is simply qE0, independent of the particle’s motion. The particle’s velocity along y is irrelevant for the electric force; it only matters if we were asked about the magnetic force.
Step-by-step solution
-
Identify the given data
- Magnetic field amplitude: B0=6 mT=6×10−3 T
- Charge: q=5 μC=5×10−6 C
- Speed of light: c=3×108 m/s
- The wave travels along +x, magnetic field along +z, so electric field is along +y (since E×B gives propagation direction). The particle moves along +y, but that does not affect the electric force magnitude.
-
Relate electric and magnetic field amplitudes
For any electromagnetic wave in vacuum,
E0=cB0
This follows from Maxwell’s equations: the ratio of field strengths is fixed by the speed of light.
- Compute the electric field amplitude E0=(3×108)×(6×10−3)=1.8×106 V/m …
-
- TG EAPCET 2026Set eng-2026-05-11-FN1 markMCQQ.If the average kinetic energy of the molecules of a gas at a temperature of 30∘C is U, then the temperature at which the average kinetic energy of the molecules of the gas becomes 2U is (A) 939∘C (B) 303∘C (C) 333∘C (D) 60∘C
›Reveal solutionSolution
The average kinetic energy of gas molecules is directly proportional to the absolute temperature (in Kelvin). Doubling the energy means doubling the Kelvin temperature, then converting back to Celsius gives 333∘C.
The key idea here is that the average kinetic energy of molecules in an ideal gas depends only on the absolute temperature — not on the type of gas, pressure, or volume. This is a direct consequence of the kinetic theory of gases.
The average kinetic energy per molecule is given by 23kBT, where kB is Boltzmann's constant and T is the absolute temperature in Kelvin. So if the energy doubles, the absolute temperature must double as well. The trap most students fall into is forgetting to convert Celsius to Kelvin before doing the ratio — Celsius is a shifted scale, not an absolute one.
Let’s work through it step by step.
-
Convert the given Celsius temperature to Kelvin.
The formula is T(K)=T(∘C)+273.
So T1=30+273=303 K.
-
Relate kinetic energy to temperature.
The average kinetic energy U∝T (in Kelvin). So if U becomes 2U, the new absolute temperature T2 must satisfy
T1T2=U2U=2.
Hence T2=2×303=606 K.
- Convert the new temperature back to Celsius. …
-
- TG EAPCET 2026Set eng-2026-05-11-AN1 markMCQQ.At a constant pressure of 2×105 Nm−2, if the volume of 4 moles of a monoatomic gas changes from 1000 cc to 1500 cc, then the change in internal energy of the gas is (A) 150 J (B) 250 J (C) 200 J (D) 600 J
›Reveal solutionSolution
At constant P: W=PΔV=100 J and for a monoatomic gas ΔU=23PΔV=150 J.
Given P=2×105 Nm−2, ΔV=1500−1000=500 cc=5×10−4 m3.
Work done by the gas at constant pressure:
W=PΔV=(2×105)(5×10−4)=100 J.
For a monoatomic ideal gas, Cv=23R and PΔV=nRΔT, so …
- TG EAPCET 2026Set eng-2026-05-11-AN1 markMCQQ.If the molar specific heat of a rigid diatomic gas at constant pressure is C, then the molar specific heat of a monoatomic gas at constant volume is (A) 52C (B) 53C (C) 75C (D) 73C
›Reveal solutionSolution
The key is to relate the given C (rigid diatomic, constant pressure) to the monatomic constant‑volume specific heat using the equipartition of energy. The answer is 73C, which corresponds to option (D).
Concept & Intuition
Molar specific heats depend on how many degrees of freedom a gas molecule has.
- A rigid diatomic molecule has 5 degrees of freedom (3 translational + 2 rotational).
- A monatomic molecule has only 3 translational degrees of freedom.
For an ideal gas, the molar specific heat at constant volume is CV=2fR, where f is the number of degrees of freedom. The constant‑pressure specific heat is CP=CV+R=2f+2R.
We are told that for the rigid diatomic gas at constant pressure, C=CPdiatomic. We want CVmonatomic in terms of C.
Step‑by‑step reasoning
- Write C for the rigid diatomic gas at constant pressure. For a rigid diatomic gas, f=5.
CVdiatomic=25R,CPdiatomic=CVdiatomic+R=27R.
Hence
C=27R.
- Express R in terms of C. From the above,
R=72C.
- Find CV for a monatomic gas. For a monatomic gas, f=3, so
CVmonatomic=23R.
- Substitute R from step 2.
- TG EAPCET 2026Set eng-2026-05-11-AN1 markMCQQ.A bar magnet of magnetic moment 1.8Am2 is free to rotate about a vertical axis passing through its centre at a place where the vertical component of earth’s magnetic field is 0.3×10−4 T and the dip angle is 45∘. If the magnet at rest in east-west direction is released, then the kinetic energy (in μJ) of the magnet when it reaches north-south direction is (A) 72 (B) 54 (C) 27 (D) 36
›Reveal solutionSolution
Rotation about a vertical axis is governed by the horizontal field BH; with dip 45∘, BH=BV=0.3×10−4T, so KE=mBH=54μJ.
The magnet rotates about a vertical axis, so only the horizontal component of the earth's field exerts a torque. With dip angle δ=45∘:
tanδ=BHBV⇒BH=tan45∘BV=BV=0.3×10−4T …
- TG EAPCET 2026Set ap-2026-05-04-FN1 markMCQQ.A bar magnet of magnetic moment 1.5Am2 is initially placed in the direction of a uniform magnetic field of 18×10−2 T. The work to be done to rotate the magnet so that its magnetic moment becomes perpendicular to the direction of the magnetic field is (A) 540 mJ (B) 135 mJ (C) 270 mJ (D) 90 mJ
›Reveal solutionSolution
The work done to rotate a magnetic dipole from alignment to perpendicular orientation equals the change in potential energy, given by W=mB, which here is 0.27 J or 270 mJ.
The key concept is the potential energy of a magnetic dipole in a uniform magnetic field. A bar magnet behaves like a magnetic dipole, and its potential energy depends on the angle between its magnetic moment m and the field B.
When the magnet is aligned with the field (θ=0∘), the system is in its lowest energy state. To rotate it to a perpendicular orientation (θ=90∘), you must do work against the torque exerted by the field. This work is stored as the increase in potential energy.
The formula for potential energy is U=−mBcosθ, where θ is the angle between m and B. The work done by an external agent to change the orientation from θ1 to θ2 is simply the difference in potential energy: W=U(θ2)−U(θ1).
Let's work through the calculation step by step.
-
Identify the given quantities.
Magnetic moment, m=1.5 Am2.
Magnetic field strength, B=18×10−2 T=0.18 T.
Initial angle, θ1=0∘ (magnet aligned with field).
Final angle, θ2=90∘ (magnet perpendicular to field).
-
Write the potential energy at each orientation.
At θ1=0∘: U1=−mBcos0∘=−mB.
At θ2=90∘: U2=−mBcos90∘=0.
-
Compute the work done.
The work required is the change in potential energy:
W=U2−U1=0−(−mB)=mB.
Substitute the values:
W=(1.5)×(0.18)=0.27 J.
- Convert to millijoules. Since 1 J=1000 mJ, …
-
- TG EAPCET 2025Set eng-2025-05-02-FN1 markMCQQ.Two moles of a gas at a temperature of 327 ∘C expands adiabatically such that its volume increases by 700%. If the ratio of the specific heat capacities of the gas is 34, then the work done by the gas is (Universal gas constant =8.3 J mol−1 K−1) (A) 14.94 kJ (B) 29.88 kJ (C) 44.82 kJ (D) 59.76 kJ
›Reveal solutionSolution
For an adiabatic process, work is done at the expense of internal energy. Using the adiabatic relation TVγ−1=constant and the formula W=γ−1nR(Ti−Tf), the work done is found to be 14.94 kJ, corresponding to option (A).
Concept & Intuition
In an adiabatic expansion, no heat enters or leaves the system (Q=0). The first law of thermodynamics then says ΔU=−W, so the work done by the gas comes entirely from a drop in its internal energy. For an ideal gas, internal energy depends only on temperature, so if we can find the final temperature after the expansion, we can compute the work directly. The key is the adiabatic relation between temperature and volume: TVγ−1=constant, where γ=Cp/Cv is given as 4/3.
Step-by-step solution
- Convert initial temperature to Kelvin The initial temperature is 327∘C.
Ti=327+273=600 K
- Interpret the volume increase “Volume increases by 700%” means the final volume is the initial volume plus 700% of it:
Vf=Vi+7Vi=8Vi
So the volume ratio is Vf/Vi=8.
- Apply the adiabatic condition For an adiabatic process, TVγ−1=constant. Thus:
TiViγ−1=TfVfγ−1
Rearranging:
Tf=Ti(VfVi)γ−1
Here γ=4/3, so γ−1=1/3.
Tf=600×(81)1/3
Since 81/3=2, we have:
Tf=600×21=300 K
- Compute the work done For an adiabatic process, the work done by the gas is: W=γ−1nR(Ti−Tf) …
- TG EAPCET 2025Set eng-2025-05-03-AN1 markMCQQ.A thin film of water is formed between two straight parallel wires each of length 8 cm separated by distance of 0.6 cm. The work done to increase the distance between the wires to 0.8 cm is (Surface tension of water = 0.07 Nm−1) (A) 33.6 μJ (B) 22.4 μJ (C) 11.2 μJ (D) 44.8 μJ
›Reveal solutionSolution
The work done equals the change in surface energy of the water film, which has two surfaces. The increase in area times surface tension times 2 gives the work: W=2×0.07×(0.08×0.002)=2.24×10−5 J=22.4 μJ, so option (B) is correct.
Concept & Intuition
A thin film of water has two free surfaces (top and bottom), each contributing to the surface energy. When you pull the wires apart, you increase the area of both surfaces. The work required is simply the increase in surface energy, because the film is in equilibrium and the only resistance comes from surface tension. The key is remembering that a film has two surfaces — a common oversight.
Step-by-step solution
-
Identify the geometry
The wires are parallel, each of length L=8 cm=0.08 m. The initial separation is d1=0.6 cm=0.006 m, and the final separation is d2=0.8 cm=0.008 m. The film is rectangular between the wires.
-
Calculate the change in area of one surface
The area of one surface of the film is L×separation.
Initial area: A1=L×d1=0.08×0.006=4.8×10−4 m2
Final area: A2=L×d2=0.08×0.008=6.4×10−4 m2
Increase in area for one surface: ΔA=A2−A1=1.6×10−4 m2
-
Account for both surfaces
The water film has two surfaces (top and bottom). So the total increase in surface area is 2×ΔA=3.2×10−4 m2. …
-
- TG EAPCET 2025Set eng-2025-05-03-FN1 markMCQQ.A thin film of water is formed between two straight parallel wires each of length 8 cm separated by distance of 0.6 cm. The work done to increase the distance between the wires to 0.8 cm is (Surface tension of water = 0.07 Nm−1) (A) 22.4 μJ (B) 33.6 μJ (C) 44.8 μJ (D) 11.2 μJ
›Reveal solutionSolution
The work done equals the change in surface energy of the film, which has two surfaces. The area increases as the wires are pulled apart, so work = surface tension × total area change = 0.07×2×(0.08×0.002)=2.24×10−5 J=22.4 μJ. The correct option is (A).
Concept & Intuition
A thin film of water between two wires has two free surfaces (top and bottom), each contributing to surface energy. Work done to stretch the film increases its surface area, and that work is stored as additional surface energy. The key formula: Work = Surface tension × Total change in surface area. Since the film has two surfaces, the total area change is twice the change in the area of one face.
Step-by-step solution
-
Identify the geometry
The wires are parallel, each of length L=8 cm=0.08 m. Initial separation d1=0.6 cm=0.006 m, final separation d2=0.8 cm=0.008 m. The film is rectangular between the wires.
-
Area of one surface
Initial area of one surface: A1=L×d1=0.08×0.006=4.8×10−4 m2
Final area of one surface: A2=L×d2=0.08×0.008=6.4×10−4 m2
Change in area of one surface: ΔAone=A2−A1=1.6×10−4 m2
-
Total area change (two surfaces)
The film has two surfaces (top and bottom), so total area change: …
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