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Example · Example 6

Q.Draw a valid Lewis structure for the carbonate ion, CO32−\text{CO}_3^{2-}, and calculate the formal charge on the carbon atom and on each oxygen atom.

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CO32−\text{CO}_3^{2-} has 4+3(6)+2=244 + 3(6) + 2 = 24 valence electrons. One valid Lewis structure places carbon centrally, doubly bonded to one oxygen and singly bonded to each of the other two oxygens, with the singly bonded oxygens each carrying three lone pairs and the doubly bonded oxygen carrying two lone pairs; this uses all 24 electrons and gives every atom an octet. Formal charge is calculated as FC=(valence electrons)−(lone-pair electrons)−12(bonding electrons)FC = (\text{valence electrons}) - (\text{lone-pair electrons}) - \tfrac{1}{2}(\text{bonding electrons}). For carbon: 44 bonding pairs (one double + two single, i.e. 88 bonding electrons around carbon), no lone pairs, so FCC=4−0−12(8)=0FC_C = 4 - 0 - \tfrac{1}{2}(8) = 0. For the doubly bonded oxygen: two lone pairs (44 electrons) plus 44 bonding electrons, so FC=6−4−12(4)=0FC = 6 - 4 - \tfrac{1}{2}(4) = 0. For each singly bonded oxygen: three lone pairs (66 …

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