Q.Determine the hybridisation of the central phosphorus atom in and relate it to the trigonal bipyramidal shape of the molecule.
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Start your 14-day free trial to unlock the full solution →Phosphorus forms five sigma bonds in and carries no lone pairs, giving a steric number of 5. To generate five equivalent hybrid orbitals, phosphorus mixes one , three and one orbital together — hybridisation. This requires promoting phosphorus's ground-state configuration so that all five valence electrons occupy separate orbitals (), which then mix into five hybrid orbitals. These five hybrid orbitals are oriented, by the geometry of mixing, toward the corners of a trigonal bipyramid — three equatorial hybrids at to one another and two axial hybrids at to the equatorial plane — exactly reproducing the trigonal bipyramidal shape (and the axial/equatorial bond-length inequivalence) that VSEPR theo …
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