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Example · Example 4

Q.Arrange NaNa, MgMg, AlAl, SiSi (Period 3) in order of decreasing atomic radius and explain the trend.

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✓ Free question

Step 1. Na,Mg,Al,SiNa, Mg, Al, Si are all Period 3 elements, so each successive atom's outer electrons occupy the same n=3n=3 shell.

Step 2. Moving from NaNa to SiSi, the nuclear charge increases by one proton at each step, while the number of inner shielding shells stays the same.

Step 3. The rising effective nuclear charge pulls the same outer shell inward more strongly at each step, so the atom shrinks.

✓Final answer

Na>Mg>Al>SiNa > Mg > Al > Si in atomic radius.

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