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Exercise · Q5

Q.Explain why atomic radius increases on descending a group, using LiLi, NaNa, KK as an example.

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✓ Free question

Step 1. Li,Na,KLi, Na, K are the first three members of Group 1, in Periods 2, 3 and 4 respectively.

Step 2. Going from LiLi to NaNa to KK, each element's outermost electron occupies a shell with a higher principal quantum number (n=2n=2, then 33, then 44).

Step 3. Even though nuclear charge also increases down the group, the effect of adding an entirely new, larger outer shell each time dominates over the extra nuclear pull, so the atom gets bigger overall.

✓Final answer

Li<Na<KLi < Na < K in atomic radius, because each step down the group adds a new principal shell.

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