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Numerical · Q16

Q.A 100 g100\ \text{g} piece of an unknown metal, initially at 150 ∘C150\,^\circ\text{C}, is dropped into 200 g200\ \text{g} of water at 25 ∘C25\,^\circ\text{C} contained in a calorimeter of negligible heat capacity. The mixture reaches a common final temperature of 30 ∘C30\,^\circ\text{C}. Taking the specific heat capacity of water as 4200 J kg−1K−14200\ \text{J kg}^{-1}\text{K}^{-1}, calculate the specific heat capacity of the metal.

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✓ Free question

Given: mmetal=0.1 kgm_{\text{metal}} = 0.1\ \text{kg} cooling from 150 ∘C150\,^\circ\text{C} to 30 ∘C30\,^\circ\text{C} (ΔTmetal=120 ∘C\Delta T_{\text{metal}} = 120\,^\circ\text{C}); mwater=0.2 kgm_{\text{water}} = 0.2\ \text{kg} warming from 25 ∘C25\,^\circ\text{C} to 30 ∘C30\,^\circ\text{C} (ΔTwater=5 ∘C\Delta T_{\text{water}} = 5\,^\circ\text{C}); cwater=4200 J kg−1K−1c_{\text{water}} = 4200\ \text{J kg}^{-1}\text{K}^{-1}.

By the principle of calorimetry, heat lost by the metal = heat gained by the water:

mmetal c ΔTmetal=mwater cwater ΔTwaterm_{\text{metal}}\,c\,\Delta T_{\text{metal}} = m_{\text{water}}\,c_{\text{water}}\,\Delta T_{\text{water}}

0.1×c×120=0.2×4200×5=42000.1 \times c \times 120 = 0.2 \times 4200 \times 5 = 4200

c=42000.1×120=420012=350 J kg−1K−1c = \frac{4200}{0.1 \times 120} = \frac{4200}{12} = 350\ \text{J kg}^{-1}\text{K}^{-1}

✓Final answer

The unknown metal's specific heat capacity is 350 J kg−1K−1350\ \text{J kg}^{-1}\text{K}^{-1}.

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