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Exercise · Q13

Q.Distinguish between the latent heat of fusion and the latent heat of vaporisation of a substance. Using the idea of latent heat, explain why a burn caused by steam at 100 ∘C100\,^\circ\text{C} is generally far more severe than a burn caused by an equal mass of boiling water at the same temperature.

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The latent heat of fusion, LfL_f, is the heat absorbed (or released) per unit mass of a substance as it changes between the solid and liquid states, at the constant melting/freezing temperature. The latent heat of vaporisation, LvL_v, is the heat absorbed (or released) per unit mass as the substance changes between the liquid and gas states, at the constant boiling/condensation temperature. For water, Lf≈3.34×105 J kg−1L_f \approx 3.34\times10^{5}\ \text{J kg}^{-1} while Lv≈2.26×106 J kg−1L_v \approx 2.26\times10^{6}\ \text{J kg}^{-1} -- nearly seven times larger -- because vaporisation must completely separate molecules from one another against the full strength of the liquid's intermolecular attraction, a far bigger undertaking than merely loosening a solid's rigid lattice into a liquid. …

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