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Question 41 of 48

Q.Which of the following compounds is known as DDT?

(a) A benzene ring bearing two Cl substituents (one ortho, one shown below the ring) attached directly to -CH2-CCl3
(b) Two benzene rings, each bearing one Cl substituent, both attached to a central -CH- which is also bonded to -CCl3 (i.e. Cl-C6H4-CH(-C6H4-Cl)-CCl3, with the two Cl atoms drawn in an ortho-like arrangement)
(c) Two benzene rings, each bearing one Cl substituent, both attached to a central -CH- which is bonded to -CHCl2 (i.e. Cl-C6H4-CH(-C6H4-Cl)-CHCl2)
(d) Two benzene rings, each bearing one Cl substituent (para position), both attached to a central -CH- which is bonded to -CCl3 (i.e. Cl-C6H4-CH(-C6H4-Cl)-CCl3) — the standard DDT structure
West Bengal WbchseWest Bengal HS (WBCHSE) Board 2025MCQ· 1mImportance★★★★★
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DDT = 1,1,1-trichloro-2,2-bis(4-chlorophenyl)ethane — two p-chlorophenyl rings on a CH carbon, with a −CCl3-CCl_3 group.

DDT (dichlorodiphenyltrichloroethane) is a well-known chlorinated organic insecticide discussed under the environmental effects of haloarenes because of its persistence and bioaccumulation (it is non-biodegradable and builds up in fatty tissue up the food chain). Structurally it consists of two chlorobenzene rings (each chlorine substituted at the para position relative to the point of attachment), both attached to a single central CH carbon, which is in turn bonded to a trichloromethyl (−CCl3-CCl_3) group: ClCl-C6H4C_6H_4-CHCH(−C6H4-C_6H_4-ClCl)- …

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