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Question 44 of 48

Q.The IUPAC name of the following compound is (a chiral carbon bonded to Br, CH3, OH and H)

(a) (1R)-1-bromoethan-1-ol
(b) (2R)-2-bromoethan-1-ol
(c) (1S)-1-bromoethan-1-ol
(d) (2S)-2-bromoethan-2-ol
West Bengal WbchseWest Bengal HS (WBCHSE) Board 2026MCQ· 1mImportance★★★★★
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A carbon bearing Br, OH, CH3 and H is 1-bromoethan-1-ol (OH gets locant 1); applying CIP priority Br > OH > CH3 > H to the depicted arrangement gives the R configuration. Correct option (a).

Naming first: the chain is only two carbons; the principal characteristic group is -OH (suffix -ol), so it gets the lowest locant. C1 carries -OH and -Br, C2 is the -CH3. Hence the name is 1-bromoethan-1-ol. This immediately eliminates options (b) '2-bromoethan-1-ol' and (d) '2-bromoethan-2-ol', which are wrong skeletons/locants.

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