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Exercise · Q13

Q.Write the microscopic expression for the resistivity of a conductor, ρ=m/(ne2τ)\rho = m/(ne^2\tau), in terms of the relaxation time τ\tau of the free electrons. Using this expression, explain why the resistivity of a metal increases as its temperature is raised.

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✓ Free question

The microscopic expression for resistivity, derived from the drift-velocity picture (Section 3.5), is

ρ=mne2τ\rho = \frac{m}{ne^2\tau}

where mm is the electron mass, nn the free-electron density, ee the electronic charge, and τ\tau the relaxation time (average time between successive collisions of a free electron with the lattice).

For a metal, the free-electron density nn is essentially fixed and does not change appreciably with temperature -- the metal's atoms are already fully ionised, contributing their free electrons regardless of temperature. As temperature rises, however, the lattice ions vibrate about their mean positions with greater amplitude, so a moving free electron collides with them MORE frequently, which directly means the relaxation time τ\tau (the average time between collisions) DECREASES.

Since ρ∝1/τ\rho \propto 1/\tau with mm, nn, ee all effectively constant, a decrease in τ\tau directly produces an INCREASE in ρ\rho, and hence in resistance R=ρl/AR=\rho l/A. This is the microscopic origin of the positive temperature coefficient of resistance observed in every ordinary metal.

✓Final answer

ρ=m/(ne2τ)\rho=m/(ne^2\tau): as temperature rises, increased lattice vibration reduces the relaxation time τ\tau, and since ρ∝1/τ\rho\propto 1/\tau, resistivity (and resistance) rises with temperature for a metal.

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