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Exercise · Q15

Q.Using the microscopic (free-electron) picture of conduction, explain why the resistance of a metallic conductor increases with a rise in temperature, while the resistance of a typical semiconductor decreases with a rise in temperature.

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✓ Free question

Both effects trace back to the same microscopic formula, ρ=m/(ne2τ)\rho = m/(ne^2\tau), but the two materials differ in WHICH quantity in this formula actually changes with temperature.

In a metal, essentially every atom already contributes its free (valence) electrons to the conduction sea, regardless of temperature -- so the free-electron density nn stays practically constant as temperature changes. The only quantity that changes is the relaxation time τ\tau, which DECREASES as temperature rises (more vigorous lattice vibration means more frequent electron-ion collisions). With nn fixed and τ\tau falling, ρ=m/(ne2τ)\rho=m/(ne^2\tau) RISES, so resistance rises with temperature.

In a semiconductor, by contrast, only a small fraction of the valence electrons are free to conduct at any given temperature (most remain bound in covalent bonds); raising the temperature supplies more thermal energy to break additional covalent bonds, releasing MORE free electrons (and correspondingly more holes) to participate in conduction. This means nn itself rises steeply -- often exponentially -- with temperature. Although τ\tau still falls somewhat (the same increased-collision effect as in a metal), the rise in nn is far larger and dominates the formula, so ρ=m/(ne2τ)\rho = m/(ne^2\tau) FALLS overall, and resistance falls with temperature.

✓Final answer

Metal: nn constant, τ\tau falls with rising TT ⇒\Rightarrow RR rises. Semiconductor: nn rises sharply with TT (more bonds broken, more free carriers), outweighing the fall in τ\tau ⇒\Rightarrow RR falls.

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