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Exercises · 11.34

Q.Boric acid is polymeric due to

(a) its acidic nature
(b) the presence of hydrogen bonds
(c) its monobasic nature
(d) its geometry
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Boric acid's units are joined into large sheets purely through intermolecular hydrogen bonding, which is the reason it is described as a polymeric solid.

  1. Structure of boric acid. Boric acid, H3BO3\text{H}_3\text{BO}_3 (or B(OH)3\text{B(OH)}_3), consists of planar, triangular units in which boron (sp2sp^2 hybridised) is bonded to three –OH groups.
  2. How these units link up. Each –OH group can act as both a hydrogen-bond donor and acceptor, so individual B(OH)3\text{B(OH)}_3 units link to their neighbours through hydrogen bonds, building up an extended two-dimensional sheet.
  3. Why this is "polymeric." This hydrogen-bonded network of repeating \text{B(OH)}_3} units extending over a large sheet is what gives boric acid its layered, polymer-like solid structure — the layers themselves are then held together only by weaker van der Waals forces (giving the solid its softness/flakiness). …

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