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Exercises · 11.36

Q.Thermodynamically the most stable form of carbon is

(a) diamond
(b) graphite
(c) fullerenes
(d) coal
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Graphite is the reference (zero-enthalpy) allotrope of carbon and lies at lower energy than diamond or fullerenes under standard conditions, making it thermodynamically the most stable form.

  1. What "thermodynamically most stable" means here. Among the possible forms of an element, the thermodynamically most stable allotrope under given (standard) conditions is the one with the lowest Gibbs free energy/enthalpy.
  2. Reference convention. Graphite is conventionally taken as the standard state of carbon, with ΔfH⊖=0\Delta_f H^\ominus = 0; diamond has a small positive standard enthalpy of formation relative to graphite (diamond is metastable — it persists at ordinary conditions due to a very high activation barrier for conversion, not because it is the lower-energy form). …

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