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Question

Q.(a) Use Einstein's photoelectric equation to depict the variation of the maximum kinetic energy (EkE_k) of electrons emitted, with the frequency (ν\nu) of the incident radiation.

(b) A photosensitive surface is illuminated with a beam of
(i) yellow light, and
(ii) red light, both of the same intensity. In which case will (I) photoelectrons have more EkE_k ? (II) more numbers of electrons be emitted ? Justify your answer in each case.
CBSECBSE Class XII Board 2022Subjective· 3mImportance★★★★★
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Einstein's photoelectric equation Ek=hν−ϕE_k = h\nu - \phi gives a straight-line graph of maximum kinetic energy versus frequency with slope hh and negative intercept −ϕ-\phi. Yellow light (higher frequency) produces photoelectrons with greater kinetic energy, while equal-intensity beams emit equal numbers of electrons per second.

The photoelectric effect reveals the particle nature of light. When photons strike a metal surface, they transfer energy in discrete packets—each photon either ejects an electron or doesn't. Einstein's insight was that the photon's energy hνh\nu must first overcome the work function ϕ\phi (the minimum energy binding an electron to the metal), and whatever remains becomes the electron's kinetic energy.

This is fundamentally different from the classical wave picture, which predicted that brighter light (more intensity) should eject electrons with more energy. Instead, we find that frequency alone determines the maximum kinetic energy, while intensity controls how many electrons escape per second.


(a) The Einstein photoelectric equation and its graph

Einstein's photoelectric equation captures the energy balance:

Ek=hν−ϕE_k = h\nu - \phi

where EkE_k is the maximum kinetic energy of emitted electrons, hh is Planck's constant, ν\nu is the frequency of incident radiation, and ϕ\phi is the work function of the material.

This is the equation of a straight line when we plot EkE_k versus ν\nu:

Key features of the graph:

  1. Slope: The gradient is hh (Planck's constant), a universal constant ≈6.63×10−34\approx 6.63 \times 10^{-34} J·s. This slope is the same for all materials.

  2. Intercept on the EkE_k axis: When ν=0\nu = 0, we get Ek=−ϕE_k = -\phi. The line crosses the vertical axis at −ϕ-\phi, below the origin.

  3. Intercept on the ν\nu axis (threshold frequency): Setting Ek=0E_k = 0 gives the threshold frequency ν0=ϕh\nu_0 = \frac{\phi}{h}. Below this frequency, no photoelectrons are emitted regardless of intensity—the photon simply lacks enough energy to free an electron.

  4. Material dependence: Different materials have different work functions, so their graphs are parallel lines (same slope hh) but shifted horizontally. A metal with larger ϕ\phi has its threshold shifted to higher frequencies.

Picture the graph rather than reading it off a diagram: plot ν\nu (frequency) along the horizontal axis and EkE_k along the vertical axis. The line crosses the horizontal axis at the threshold frequency ν0\nu_0 (no photoelectrons at all for ν<ν0\nu < \nu_0), it would cross the vertical axis at −ϕ-\phi if extended backward (not a physically attainable point, since no emission happens there), and for every ν>ν0\nu > \nu_0 it rises as a dead-straight line with constant slope hh — the slope never changes because hh is a universal constant, the same for every material.

The graph starts at ν=ν0\nu = \nu_0 (no emission below this) and rises linearly thereafter.

Tip

The universality of the slope hh was crucial experimental evidence for quantum theory. Millikan's careful measurements of this slope for different materials all yielded the same value, confirming Einstein's equation and earning him the Nobel Prize.


(b) Comparing yellow and red light of equal intensity

Both beams have the same intensity, meaning they deliver the same power per unit area. Since intensity I=NhνAtI = \frac{N h \nu}{A t} (number of photons NN per area AA per time tt, each carrying energy hνh\nu), equal intensity with different frequencies means different photon fluxes.

Yellow light has higher frequency than red light: νyellow>νred\nu_{\text{yellow}} > \nu_{\text{red}}.

(I) Which photoelectrons have more EkE_k?

From Einstein's equation, the maximum kinetic energy depends only on frequency:

Ek=hν−ϕE_k = h\nu - \phi

Since νyellow>νred\nu_{\text{yellow}} > \nu_{\text{red}}, we have:

Ek,yellow=hνyellow−ϕ>hνred−ϕ=Ek,redE_{k,\text{yellow}} = h\nu_{\text{yellow}} - \phi > h\nu_{\text{red}} - \phi = E_{k,\text{red}}

Photoelectrons emitted by yellow light have greater maximum kinetic energy. Each yellow photon is more energetic, so after paying the "exit fee" ϕ\phi, more energy remains for the electron's motion.

Watch out

A common mistake is to think that higher intensity automatically means higher kinetic energy. Intensity affects the number of photons, not the energy of each photon. Only frequency determines individual photon energy and hence EkE_k. …

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