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Q.Radiation of wavelength 200200 nm is incident on a photosensitive surface of work function 4.24.2 eV. The kinetic energy of the fastest photoelectrons emitted from this surface will be close to : (A) 3.53.5 eV (B) 3.03.0 eV (C) 2.52.5 eV (D) 2.02.0 eV

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The fastest photoelectron’s kinetic energy is found from Einstein’s photoelectric equation: Kmax=hν−ϕK_{\text{max}} = h\nu - \phi. Converting wavelength to frequency and using the given work function gives Kmax≈2.0K_{\text{max}} \approx 2.0 eV, so the correct option is (D).

The photoelectric effect is a clean, direct application of energy conservation: a photon gives all its energy to an electron. The electron uses some of that energy to escape the surface (the work function ϕ\phi), and whatever remains shows up as kinetic energy. The fastest electron is the one that loses the least energy on its way out — so its kinetic energy is simply hν−ϕh\nu - \phi.

Let’s walk through it.

  1. Find the photon energy in eV. Wavelength λ=200\lambda = 200 nm =200×10−9= 200 \times 10^{-9} m. Photon energy E=hν=hcλE = h\nu = \frac{hc}{\lambda}. Use the handy constant hc=1240hc = 1240 eV·nm (this is a standard shortcut for such problems). So

E=1240 eV⋅nm200 nm=6.2 eV.E = \frac{1240\ \text{eV·nm}}{200\ \text{nm}} = 6.2\ \text{eV}.

Tip

Memorise hc≈1240hc \approx 1240 eV·nm — it converts wavelength in nm directly to energy in eV without messing with SI units.

  1. Apply Einstein’s photoelectric equation. The maximum kinetic energy of emitted photoelectrons is

Kmax=hν−ϕ.K_{\text{max}} = h\nu - \phi.

Here ϕ=4.2\phi = 4.2 eV. So

Kmax=6.2 eV−4.2 eV=2.0 eV.K_{\text{max}} = 6.2\ \text{eV} - 4.2\ \text{eV} = 2.0\ \text{eV}. …

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