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Q.The variation of the stopping potential (V0)(V_0) with the frequency (ν)(\nu) of the incident radiation for four metals A, B, C and D is shown in the figure. For the same frequency of incident radiation producing photo-electrons in all the metals, the kinetic energy of the photo-electrons will be maximum for metal ______.
(A) A
(B) B
(C) C
(D) D

Figure: stopping potential V0 vs frequency graph for metals A, B, C, D
Figure
CBSECBSE Class XII Board 2024MCQ· 1mImportance★★★★★
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The stopping potential V0V_0 vs. frequency ν\nu graph gives straight lines of equal slope h/eh/e for all metals. The metal with the smallest threshold frequency ν0\nu_0 (where its line meets the ν\nu-axis) has the smallest work function. For a fixed incident frequency, the maximum kinetic energy Kmax=h(ν−ν0)K_{\text{max}} = h(\nu - \nu_0) is largest for the metal with the smallest ν0\nu_0 — which is metal A.

The photoelectric effect is beautifully simple once you see it through Einstein’s equation. When light of frequency ν\nu hits a metal, each photon gives its energy hνh\nu to an electron. The electron must first overcome the metal’s work function ϕ\phi (the minimum energy to escape). Whatever energy remains becomes the electron’s maximum kinetic energy:

Kmax=hν−ϕK_{\text{max}} = h\nu - \phi

The stopping potential V0V_0 is the voltage that just stops the most energetic electrons, so eV0=KmaxeV_0 = K_{\text{max}}. Hence:

eV0=hν−ϕeV_0 = h\nu - \phi

Rearranging:

V0=heν−ϕeV_0 = \frac{h}{e}\nu - \frac{\phi}{e}

This is a straight line when you plot V0V_0 against ν\nu. The slope is h/eh/e — the same for every metal because Planck’s constant hh and the electron charge ee are universal constants. That’s why all four lines in the figure are parallel.

The intercept on the ν\nu-axis (where V0=0V_0 = 0) gives the threshold frequency ν0\nu_0:

0=heν0−ϕe⇒ϕ=hν00 = \frac{h}{e}\nu_0 - \frac{\phi}{e} \quad\Rightarrow\quad \phi = h\nu_0

So the metal with the smallest ν0\nu_0 has the smallest work function ϕ\phi.

Now, for a fixed incident frequency ν\nu (the same for all metals), the maximum kinetic energy is:

Kmax=hν−ϕ=h(ν−ν0)K_{\text{max}} = h\nu - \phi = h(\nu - \nu_0)

Since hh and ν\nu are constant, KmaxK_{\text{max}} is largest when ν0\nu_0 is smallest.

Figure: stopping potential V0 vs frequency graph for metals A, B, C, D
Figure: stopping potential V0 vs frequency graph for metals A, B, C, D
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