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Exercise · Q42

Q.Identify the main product of the reaction.
CH3-CH(OH)-CH3 --60% H2SO4, 373K-->

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Step 1. Identify the reaction. CH3-CH(OH)-CH3 (propan-2-ol) heated with H2SO4 is acid-catalysed dehydration, section 15.2.2.

Step 2. Apply beta-elimination. The -OH leaves C2; a beta-hydrogen must leave an adjacent carbon (C1 or C3, which are equivalent methyl groups by the molecule's symmetry) -- so only one distinct alkene is geometrically possible here. …

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