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Exercise · Q33

Q.Name the following: Write the balanced chemical reaction for preparation of ethane from
a. Ethyl bromide b. Ethyl magnesium iodide

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Step 1. Route a -- from ethyl bromide. Section 15.1.3 describes reduction of an alkyl halide with zinc and dilute HCl, which generates nascent hydrogen that replaces the halogen: CH3CH2Br + 2[H] (from Zn, dil. HCl) gives CH3CH3 (ethane) + HBr.

Step 2. Route b -- from ethyl magnesium iodide. Ethylmagnesium iodide (CH3CH2MgI) is itself a Grignard reagent (already prepared, in this question, from ethyl iodide + Mg/dry ether in an earlier step not shown here); reacting it with water hydrolyses it directly to the alkane: CH3CH2MgI + H2O (dry ether) gives CH3CH3 (ethane) + Mg(OH)I. …

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