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Question 82 of 88

Q.Identify 'A', 'B' and 'C' in following chain reaction and rewrite the chemical reactions: CH3CH2OH→Br2red ′P′A→alcKCNB→EtherLiAlH4CCH_3CH_2OH \xrightarrow[Br_2]{red\ 'P'} A \xrightarrow[alc]{KCN} B \xrightarrow[Ether]{LiAlH_4} C

Maharashtra MsbshseMaharashtra HSC (MSBSHSE) Board 2024Subjective· 3mImportance★★★★★
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A=C2H5BrC_2H_5Br (from red P/Br2_2), B=C2H5CNC_2H_5CN (from alc. KCN), C=CH3CH2CH2NH2CH_3CH_2CH_2NH_2 (LiAlH4_4 reduction).

CH3CH2OH→Δred P/Br2ACH_3CH_2OH \xrightarrow[\Delta]{red\ P/Br_2} A: red phosphorus + bromine generates PBr3PBr_3 in situ, which converts the alcohol to the alkyl bromide:

C2H5OH⟶C2H5BrC_2H_5OH \longrightarrow C_2H_5Br (A = ethyl bromide)

A→alc. KCNBA \xrightarrow{alc.\ KCN} B: ethyl bromide reacts with (ionic) potassium cyanide via the carbon end, giving the nitrile:

C2H5Br+KCN⟶C2H5CNC_2H_5Br + KCN \longrightarrow C_2H_5CN (B = ethyl cyanide / propanenitrile)

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