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Question 81 of 115

Q.Absolute entropies of solids, liquids and gases can be determined by _______.

(a) measuring heat capacity of substance at various temperatures
(b) subtracting standard entropy of reactants from products
(c) measuring vibrational motion of molecules
(d) using formula ΔS∘=ST∘−S0∘\Delta S^\circ = S^\circ_T - S^\circ_0
Maharashtra MsbshseMaharashtra HSC (MSBSHSE) Board 2016MCQ· 1mImportance★★★★★
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Absolute entropy is determined from heat capacity measurements over a range of temperatures.

According to the third law of thermodynamics, the entropy of a perfectly crystalline substance is zero at absolute zero (0 K). Absolute entropy at any temperature T is then obtained experimentally by measuring the heat capacity (CpC_p) of the substance at a series of temperatures from near 0 K up to T, and evaluating ST∘=∫0TCpT dTS^\circ_T = \int_0^T \dfrac{C_p}{T}\,dT. This is why option (a) — measuring heat capacity of the sub …

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