Question 86 of 115
Q.State third law of thermodynamics. Give 'two' uses.
Maharashtra MsbshseMaharashtra HSC (MSBSHSE) Board 2018Subjective· 2mImportance★★★★★
75% · 86/115 Questions
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Start your 14-day free trial to unlock the full solution →Perfect crystals have zero entropy at 0 K; this lets us compute absolute entropies and detect crystal imperfections.
Third law of thermodynamics: the entropy of a pure, perfectly crystalline substance is exactly zero at the absolute zero of temperature (0 K), since at 0 K the constituent particles are in a single, perfectly ordered arrangement with no thermal disorder — there is only one possible microstate, so .
Two uses:
- Unlike enthalpy or internal energy (for which only changes, /, can be measured), the third law gives an absolute zero-point reference for entropy, so the absolute entropy () of any substance at any temperature can be calculated by integrating heat-capacity data from 0 K up to . …
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