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Question 111 of 115

Q.(a) State whether entropy change is positive or negative in the following examples:

(i) Melting of ice
(ii) Vaporisation of a liquid.
(b) Explain 'common ion effect' with example.
Maharashtra MsbshseMaharashtra HSC (MSBSHSE) Board 2025Subjective· 4mImportance★★★★★
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Melting ice and vaporisation both have ΔS>0\Delta S>0 (increased disorder). Common ion effect: a shared ion from a strong electrolyte suppresses a weak electrolyte's dissociation (e.g. CH3_3COONa on CH3_3COOH).

(a)(i) Melting of ice: solid → liquid; molecules go from a rigid, ordered lattice to a more disordered, mobile liquid state, so randomness increases: ΔS>0\Delta S > 0 (positive).

(a)(ii) Vaporisation of a liquid: liquid → gas; molecules go from being close together to widely separated and moving freely, a large increase in disorder: ΔS>0\Delta S > 0 (positive).

(b) Common ion effect: the suppression of the degree of dissociation (ionisation) of a weak electrolyte, caused by adding a strong electrolyte that shares a common ion with it, by Le Chatelier's principle.

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