Q.(a) State whether entropy change is positive or negative in the following examples:
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Start your 14-day free trial to unlock the full solution →Melting ice and vaporisation both have (increased disorder). Common ion effect: a shared ion from a strong electrolyte suppresses a weak electrolyte's dissociation (e.g. CHCOONa on CHCOOH).
(a)(i) Melting of ice: solid → liquid; molecules go from a rigid, ordered lattice to a more disordered, mobile liquid state, so randomness increases: (positive).
(a)(ii) Vaporisation of a liquid: liquid → gas; molecules go from being close together to widely separated and moving freely, a large increase in disorder: (positive).
(b) Common ion effect: the suppression of the degree of dissociation (ionisation) of a weak electrolyte, caused by adding a strong electrolyte that shares a common ion with it, by Le Chatelier's principle.
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