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Chemistry · Ch 5 — Electrochemistry

Conductivity (k)

5.3.1

Conductivity (k)

We have seen that G=1/RG = 1/R and that RR is directly proportional to length and inversely proportional to cross-sectional area. It therefore follows that GG is directly proportional to aa and inversely proportional to ll:

G∝al    or    G=k al...(5.4)G \propto \frac{a}{l} \;\; \text{or} \;\; G = k\,\frac{a}{l} \qquad \text{...(5.4)}

The proportionality constant kk is called conductivity. G=kG = k if the length and cross-sectional area of the conductor are unity. Conductivity is thus the electrical conductance of a conductor of unit length and unit area of cross section — in other words, the electrical conductance of a unit cube (1 m3\mathrm{1\ m^3} or 1 cm3\mathrm{1\ cm^3}) of material. The conductivity of a solution of an electrolyte is called electrolytic conductivity, which refers to the electrical conductance of unit volume of the solution.

From Eq. (5.2) and Eq. (5.4) we write

k=G la=1R⋅la...(5.5)k = G\,\frac{l}{a} = \frac{1}{R}\cdot\frac{l}{a} \qquad \text{...(5.5)}

Combination of Eq. (5.3) and Eq. (5.5) shows that k=1/ρk = 1/\rho — conductivity is the inverse of resistivity.

Units of electrolytic conductivity

| Quantity | SI unit | Common unit |

|---|---|---| …