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Answer the following · Q13

Q.xiii. Which of the following species are reducing agents? Arrange them in order of increasing strength under standard state conditions. The standard potentials are given in parenthesis. K (-2.93V), Br2_2(1.09V), Mg(-2.36V), Ce3+^{3+}(1.61V), Ti2+^{2+}(-0.37V), Ag+^+(0.8 V), Ni (-0.23V).

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Step 1. From K(-2.93V), Br2(1.09V), Mg(-2.36V), Ce3+(1.61V), Ti2+(-0.37V), Ag+(0.8V), Ni(-0.23V): the REDUCING agents are the reduced-form species capable of donating electrons -- K, Mg, Ti2+, Ni, and (weakly) Ce3+, the reduced form of the Ce4+/Ce3+ couple.

Step 2. Br2 and Ag+ are both OXIDISED-form species (oxidising agents), so they are excluded from the reducing-agent list. …

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