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Problems · Problem 3.7

Q.A weak monobasic acid is 0.04 % dissociated in 0.025M solution. What is pH of the solution ?

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[H3O+]=αc=10−5[\mathrm{H_3O^+}] = \alpha c = 10^{-5} M gives pH =5= 5.

Step 1. Convert the percent dissociation to a fraction: α=0.04%=0.04100=4×10−4\alpha = 0.04\% = \dfrac{0.04}{100} = 4\times10^{-4}.

Step 2. Each dissociated acid molecule supplies one H3O+\mathrm{H_3O^+}: [H3O+]=αc=4×10−4×0.025=1×10−5[\mathrm{H_3O^+}] = \alpha c = 4\times10^{-4}\times0.025 = 1\times10^{-5} M. …

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